银配合物的合成、结构和荧光性质研究

Simple item page
dc.contributor.advisor杨士烑
dc.contributor.author黄华奇
dc.date.accessioned2022-01-12T07:25:16Z
dc.date.available2022-01-12T07:25:16Z
dc.date.issued2018-12-28
dc.date.replied2018-11-03
dc.description.abstract由于具有丰富的结构和多样的性能，近二三十年来配合物是科研的热点领域。实现对配合物结构和性质的控制是晶体工程的重要目标。然而，配合物自组装反应受金属离子、配体、阴离子、溶剂等很多因素的影响。一价银离子具有$d^{10}$的电子构型，配位几何多变，且可能形成亲银作用，银配合物还可能具有荧光性质。本文进行了一些N配位原子配体，羧酸配体与银离子在不同溶剂体系下的配位聚合物合成和性质研究。主要工作如下： 1、使用银盐和樟脑酸分别与两个吡嗪衍生物配体反应，合成了四个银的配位聚合物：\ce{[Ag2(tpyz)L]_n}(1)，\ce{[Ag4(tpyz)2L2]_n}(2)，\\\ce{[Ag2(m...
dc.description.abstractDue to their abundant structural patterns and various properties for potential applications, coordination compounds have attracted great attention for the past few decades. To get control over the structures and properties of coordination compounds is an important goal in crystal engineering. However, self-assembly process is affected by many factors, including metal ions, ligands, anion and solve...
dc.description.note学位：理学硕士
dc.description.note院系专业：化学化工学院_无机化学
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/198311
dc.language.isozh_CN
dc.source.urihttps://etd.xmu.edu.cn/detail.asp?serial=5EE7EE79-2A33-479A-9537-5D523F654144
dc.subject银
dc.subject吡嗪
dc.subject咪唑
dc.subject配合物
dc.subject羧酸
dc.subject溶剂
dc.subjectsilver
dc.subjectpyrazine
dc.subjectimidazole
dc.subjectcoordination compounds
dc.subjectcarboxylate
dc.title银配合物的合成、结构和荧光性质研究
dc.title.alternativeSynthesisθ structure and luminesence of silver complexes
dc.typethesis

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
银配合物的合成、结构和荧光性质研究.pdf
Size:
423.01 KB
Format:
Adobe Portable Document Format
Download

Collections

化学化工－学位论文